Packaging and storage—
Preserve in tight cylinders, and prevent exposure to excessive heat.
Identification—
A:
The IR absorption spectrum of it exhibits maxima, among others, at about the following wavelengths, in µm: 3.4 (vs), 6.8 (s), and 7.2 (m).
Acidity of residue—
Add 10 mL of water to the residue obtained in the test for
High-boiling residues, mix by swirling for about 30 seconds, add 2 drops of
methyl orange TS, insert the stopper in the tube, and shake vigorously: no pink or red color appears in the aqueous layer.
Limit of sulfur compounds—
Carefully open the container valve to produce a moderate flow of gas. Do not direct the gas stream toward the face, but deflect a portion of the stream toward the nose: the odor is free from the characteristic odor of sulfur compounds.
Assay—
Chromatographic system—
Under typical conditions, the gas chromatograph is equipped with a thermal-conductivity detector and contains a 6-m × 3-mm aluminum column packed with 10 weight percent of liquid phase G30 on non-acid-washed support S1C, helium is used as the carrier gas at a flow rate of 50 mL per minute, and the temperature of the column is maintained at 33
.
System suitability—
The peak responses obtained for Propane in the chromatograms from duplicate determinations agree within 1%.
Procedure—
Connect 1 Propane cylinder to the chromatograph through a suitable sampling valve and a flow control valve downstream from the sampling valve. Flush the liquid specimen through the sampling valve, taking care to avoid entrapment of gas or air in the sampling valve. Inject a suitable volume, typically 2 µL, of Propane into the chromatograph, and record the chromatogram. Calculate the percentage purity by dividing 100 times the propane response by the sum of all of the responses in the chromatogram.
601
), determined at 21